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Available Thermodynamic Databases

A comprehensive overview of all thermodynamic databases available in MAGEMin, including their acronyms, chemical systems, phases, and primary references.

Important

The acronyms are used to construct the bulk-rock input file for the app, and link the bulk to a targeted database. The acronyms are also used when using MAGEMin_C to initialize MAGEMin_C.jl with the desired database.

Quick Reference Table

AcronymNameVersionPrimary Reference
mpMetapelitev1.3.0White et al., 2014a, 2014b
umUltramaficv1.3.2Evans & Frost, 2021
mbMetabasitev1.3.5Green et al., 2016
mtlMantlev1.5.5Holland et al., 2013
igIgneousv1.6.2Green et al., 2025 (updated from Holland et al., 2018)
igadIgneous alkalinev1.6.2Weller et al., 2024
sb11Mantle (Stixrude & Lithgow-Bertelloni)v1.7.7Stixrude & Lithgow-Bertelloni, 2011
sb21Mantle (Stixrude & Lithgow-Bertelloni)v1.7.7Stixrude & Lithgow-Bertelloni, 2021
sb24Mantle (Stixrude & Lithgow-Bertelloni)v1.8.0Stixrude & Lithgow-Bertelloni, 2024
umeUltramafic extendedEvans & Frost, 2021 + Green et al., 2016
mpeExtended metapeliteWhite et al., 2014 + Green et al., 2016 + Franzolin et al., 2011 + Diener et al., 2007
mbeExtended metabasiteGreen et al., 2016 + Diener et al., 2007 + Rebay et al., 2022

Detailed Database Descriptions

The metapelitic model (extended with MnO, White et al., 2014) allows to compute the mineral assemblage from low temperature to supra-solidus conditions.

  • Added March 2023, `MAGEMin v1.3.0`
  • White et al., 2014a, 2014b (see http://hpxeosandthermocalc.org)
  • K2O-Na2O-CaO-FeO-MgO-Al2O3-SiO2-H2O-TiO2-O-MnO chemical system
  • Pure stoichiometric phases quartz (q), cristobalite (crst), tridymite (trd), coesite (coe), stishovite (stv), kyanite (ky), sillimanite (sill), andalusite (and), rutile (ru), corundum (cor) and sphene (sph).
  • Solution phases spinel (spl), biotite (bi), cordierite (cd), orthopyroxene (opx), epidote (ep), garnet (g), ilmenite (ilm), silicate melt (liq), muscovite (mu), ternary feldspar (pl4T), sapphirine (sa), staurolite (st), magnetite (mt), chlorite (chl), chloritoid (ctd) and margarite (ma).

Important Notes

Important

The datasets are only calibrated for a limited range of P, T, and bulk rock conditions. If you go too far outside those ranges, MAGEMin (or most other thermodynamic software packages for that matter) may not converge or give bogus results.

Important

Developing new, more widely applicable, thermodynamic datasets is a huge research topic, which will require funding to develop the models themselves, as well as to perform targeted experiments to calibrate those models.

Warning

For most users, we recommend starting with the relevant single-system database (mp, um, mb, ig, igad, or mtl) before exploring extended/composite databases. When using extended database, mind that all phases are active by default and that the user needs to selected the adequate subset.


Reference Citations

  • Green, E.C.R., Holland, T.J.B., Powell, R., Weller, O.M., & Riel, N. (2025). Journal of Petrology, 66. doi: 10.1093/petrology/egae079

  • Weller, O.M., Holland, T.J.B., Soderman, C.R., Green, E.C.R., Powell, R., Beard, C.D., & Riel, N. (2024). New Thermodynamic Models for Anhydrous Alkaline-Silicate Magmatic Systems. Journal of Petrology, 65. doi: 10.1093/petrology/egae098

  • Holland, T.J.B., Green, E.C.R., & Powell, R. (2022). A thermodynamic model for feldspars in KAlSi₃O₈-NaAlSi₃O₈-CaAl₂Si₂O₈ for mineral equilibrium calculations. Journal of Metamorphic Geology, 40, 587-600. doi: 10.1111/jmg.12639

  • Tomlinson, E.L., & Holland, T.J.B. (2021). A Thermodynamic Model for the Subsolidus Evolution and Melting of Peridotite. Journal of Petrology, 62. doi: 10.1093/petrology/egab012

  • Holland, T.J.B., Green, E.C.R., & Powell, R. (2018). Melting of Peridotites through to Granites: A Simple Thermodynamic Model in the System KNCFMASHTOCr. Journal of Petrology, 59, 881-900. doi: 10.1093/petrology/egy048

  • Green, E.C.R., White, R.W., Diener, J.F.A., Powell, R., Holland, T.J.B., & Palin, R.M. (2016). Activity-composition relations for the calculation of partial melting equilibria in metabasic rocks. Journal of Metamorphic Geology, 34, 845-869. doi: 10.1111/jmg12211

  • White, R.W., Powell, R., Holland, T.J.B., Johnson, T.E., & Green, E.C.R. (2014). New mineral activity-composition relations for thermodynamic calculations in metapelitic systems. Journal of Metamorphic Geology, 32, 261-286. doi: 10.1111/jmg.12071

  • Holland, T.J.B., & Powell, R.W. (2011). An improved and extended internally consistent thermodynamic dataset for phases of petrological interest, involving a new equation of state for solids. Journal of Metamorphic Geology, 29, 333-383. doi: 10.1111/j.1525-1314.2010.00923.x

  • Stixrude, L., & Lithgow-Bertelloni, C. (2011). Thermodynamics of mantle minerals - II. Phase equilibria. Geophysical Journal International, 184, 1456-1475. doi: 10.1111/j.1365-246X.2010.04890.x

  • Stixrude, L., & Lithgow-Bertelloni, C. (2021). Thermal expansivity, heat capacity and isothermal compressibility of the mantle. Geophysical Journal International, 228, 1296-1314. doi: 10.1093/gji/ggab394

  • Stixrude, L., & Lithgow-Bertelloni, C. (2024). Thermodynamics of mantle minerals – III: the role of iron. Geophysical Journal International, 237(3), 1699-1733. doi: 10.1093/gji/ggae126

  • Evans, K.A., & Frost, B.R. (2021). Deserpentinization in Subduction Zones as a Source of Oxidation in Arcs: a Reality Check. Journal of Petrology, 62(3), egab016. doi: 10.1093/petrology/egab016

  • Diener, J.F.A., Powell, R., White, R.W., & Holland, T.J.B. (2007). A new thermodynamic model for clino- and orthoamphiboles in the system Na₂O-CaO-FeO-MgO-Al₂O₃-SiO₂-H₂O-O. Journal of Metamorphic Geology, 25, 631-656.

  • Rebay, G., Powell, R., & Diener, J.F.A. (2022). New activities for the system FeO-MgO-Al₂O₃-SiO₂ with applications to metamorphic rocks. Journal of Metamorphic Geology.

  • Franzolin, E., Schmidt, M.W., & Poli, S. (2011). Ternary Ca–Fe–Mg carbonates: subsolidus phase relations at 3.5 GPa and a thermodynamic solid solution model including order/disorder. Contributions to Mineralogy and Petrology, 161(2), 213-227.